Publications

The anchoring energy of liquid crystals was shown to be tunable by surface nanopatterning of periodic lines and spaces. Both the pitch and height were varied using hydrogen silsesquioxane negative tone electron beam resist, providing for flexibility in magnitude and spatial distribution of the anchoring energy. Using twisted nematic liquid...

Dynamic photoacoustic spectroscopy (DPAS) is a high sensitivity technique for standoff detection of trace vapors. A field-portable DPAS system has potential as an early warning provider for gaseous-based chemical threats. For the first time, we utilize DPAS to successfully detect the presence of trace aerosols. Aerosol identification via long-wavelength infrared...

An uncooled thermal imager is being developed based on a liquid crystal transducer. The liquid crystal transducer changes a long-wavelength infrared scene into a visible image as opposed to an electric signal in microbolometers. This approach has the potential for making a more flexible thermal sensor. One objective is to...

Early warning of the presence of chemical agent aerosols is an important component in the defense against such agents. A Raman spectrometer has been constructed for the purpose of detecting and identifying chemical aerosols. We report the detection and identification of a low-concentration chemical aerosol in atmospheric air using 532-nm...

Avalanche photodiodes (APDs) have been fabricated in order to determine the impact ionization coefficients of electrons (alpha) and holes (beta) in AlxGa1-xAsySb1-y lattice matched to GaSb for three alloy compositions: (x=0.40, y=0.035), (x=0.55, y=0.045), and (x=0.65, y=0.054). The impact ionization coefficients were calculated from photomultiplication measurements made on specially designed...

Lincoln Laboratory of Massachusetts Institute of Technology has developed a technique known as dynamic photoacoustic spectroscopy (DPAS) that could enable remote detection of trace gases via a field-portable laser-based system. A fielded DPAS system has the potential to enable rapid, early warning of airborne chemical threats. DPAS is a new...

An MS-based framework was developed to quantitatively assess API ion-molecule reagent chemistries based on ammonium selectivity versus competing ions, and intrinsic ammonium binding strength and complex survivability for detection. Methyl acetoacetate is an attractive ammonium reagent for vapor-phase API techniques given its high vapor pressure, preferential selectivity, and high critical...

Tactical high-energy laser (HEL) systems face a range of imaging-related challenges in wavefront sensing, acquiring and tracking targets, selecting the HEL aimpoint, and assessing lethality. Accomplishing these functions in a timely fashion may be limited by competing requirements on total field of regard, target resolution, signal to noise, and focal...

Etching of indium tin oxide (ITO) thin films in high density chlorine plasmas is studied, with the goal of increasing the etching selectivity to photoresist. The ITO etching rate increases with ethylene addition, but is not affected by BCl3 addition. ITO exhibits a threshold energy for ion etching, whereas the...

Single-pulse irradiation of Au and Ag suspensions of nanospheres and nanodisks with 532-nm 4-ns pulses has identified complex optical nonlinearities while minimizing material damage. For all materials tested, we observe competition between saturable absorption (SA) and reverse SA (RSA), with RSA behavior dominating for intensities above ~50 MW/cm^2. Due to...