Publications
Raman spectra and cross sections of ammonia, chlorine, hydrogen sulfide, phosgene, and sulfur dioxide toxic gases in the fingerprint region 400-1400 cm-1
Summary
Summary
Raman spectra of ammonia (NH3), chlorine (Cl2), hydrogen sulfide (H2S), phosgene (COCl2), and sulfur dioxide (SO2) toxic gases have been measured in the fingerprint region 400-1400 cm-1. A relatively compact ( 2'x2'x2'), sensitive, 532 nm 10 W CW Raman system with double-pass laser and double-sided collection was used for these...
Reagent approaches for improved detection of chlorate and perchlorate salts via thermal desorption and ionization
Summary
Summary
RATIONALE: Techniques for improving the detectability of chlorate and perchlorate salts with thermal desorption based ionizers (i.e. radioactive, corona discharge and photoionization-based) are desired. This work employs acidic reagents to chemically transform chlorate and perchlorate anions into traces of chloric and perchloric acid. These high vapor pressure acids are easier...
Photothermal speckle modulation for noncontact materials characterization
Summary
Summary
We have developed a noncontact, photothermal materials characterization method based on visible-light speckle imaging. This technique is applied to remotely measure the infrared absorption spectra of materials and to discriminate materials based on their thermal conductivities. A wavelength-tunable (7.5-8.7 um), intensity-modulated, quantum cascade pump laser and a continuous-wave 532 nm...
Super-resolution microscopy by movable thin-films with embedded microspheres: resolution analysis
Summary
Summary
Microsphere-assisted imaging has emerged as an extraordinary simple technique of obtaining optical super-resolution. This work addresses two central problems in developing this technology: i) methodology of the resolution measurements and ii) limited field-of-view provided by each sphere. It is suggested that a standard method of resolution analysis in far-field microscopy...
Versatile alignment layer method for new types of liquid crystal photonic devices
Summary
Summary
Liquid crystal photonic devices are becoming increasingly popular. These devices often present a challenge when it comes to creating a robust alignment layer in pre-assembled cells. In this paper, we describe a method of infusing a dye into a microcavity to produce an effective photo-definable alignment layer. However, previous research...
Sensitive detection and identification of isovanillin aerosol particles at the pg/cm^3 mass concentration level using Raman spectroscopy
Summary
Summary
A compact Raman spectroscopy system with high sensitivity to chemical aerosols has been developed. This system has been used to detect isovanillin aerosols with mass concentration of 12 pg/cm3 in a 15 s signal integration period with a signal-to-noise ratio of 32. We believe this represents the lowest chemical aerosol...
In situ microfluidic SERS assay for monitoring enzymatic breakdown of organophosphates
Summary
Summary
In this paper, we report on a method to probe the breakdown of the organophosphate (OP) simulants o, s-diethyl methyl phosphonothioate (OSDMP) and demeton S by the enzyme organophosphorous hydrolase (OPH) in a microfluidic device by surface enhanced Raman spectroscopy (SERS). SERS hotspots were formed on-demand inside the microfluidic device...
Coherent beam-combining of quantum cascade amplifier arrays
Summary
Summary
We present design, packaging and coherent beam combining of quantum cascade amplifier (QCA) arrays, measurements of QCA phase noise, the drive-current-to-optical-phase transfer function, and the small signal gain for QCAs.
Permittivity evaluation of multilayered hyperbolic metamaterials: ellipsometry vs. reflectometry
Summary
Summary
Metal-dielectric nanolaminates represent a class of hyperbolic metamaterials with uniaxial permittivity tensor. In this study, we critically compare permittivity extraction of nanolaminate samples using two techniques: polarized reflectrometry vs. spectroscopic anisotropic ellipsometry. Both Au/MgF2 and Ag/MgF2 metal-dielectric stacks are examined. We demonstrate the applicability of the treatment of the multilayered...
Nanochannel fabrication based on double patterning with hydrogen silsesquioxane
Summary
Summary
A double patterning process is presented to pattern sub-35 nm wide channels in hydrogen silsesquioxane with near 100% pattern densities. Using aligned electron beam lithography, each side of the nanochannel structure is patterned as a separate layer. A 50000 uC/cm^2 high-dose anneal is applied to the first layer after exposure...