Publications
Reagent assessment for detection of ammonium ion-molecule complexes
Summary
Summary
An MS-based framework was developed to quantitatively assess API ion-molecule reagent chemistries based on ammonium selectivity versus competing ions, and intrinsic ammonium binding strength and complex survivability for detection. Methyl acetoacetate is an attractive ammonium reagent for vapor-phase API techniques given its high vapor pressure, preferential selectivity, and high critical...
Measurement of trace explosive residues in a surrogate operational environment: implications for tactical use of chemical sensing in C-IED operations
Summary
Summary
A campaign to measure the amount of trace explosive residues in an operational military environment was conducted on May 27?31, 2007, at the National Training Center at Fort Irwin, CA, USA. The objectives of this campaign were to develop the methods needed to collect and analyze samples from tactical military...
Detection of condensed-phase explosives via laser-induced vaporization, photodissociation, and resonant excitation
Summary
Summary
We investigate the remote detection of explosives via a technique that vaporizes and photodissociates the condensed-phase material and detects the resulting vibrationally excited NO fragments via laser-induced fluorescence. The technique utilizes a single 7 ns pulse of a tunable laser near 236:2nm to perform these multiple processes. The resulting blue-shifted...